(Solved): By using Microsoft Excel solve these: The Van Der Waals equation of state is given by: (P+V2a)(V ...
By using Microsoft Excel solve these:
The Van Der Waals equation of state is given by: (P+V2a?)(V?b)=RT (A.1) where a=6427?(Pe?R2Te2??) (A.2) and b=8Pc?RTc?? (A.3) where P is the pressure ( atm),V is the molar volume (Lg?1mol?1),T is the temperature (K),R is the gas constant (R=0.08206atmL?1mol?1K?1), Tc? is the critical temperature (405.5K for ammoammonia). Reduced pressure is defined as Pr?=Pc?P? and the compressibility factor is given by Z=RTPV? Using Newton Raphson numerical method and Excel:
1. Calculate the molar volume (V) and compressibility factor (Z) for gaseous ammonia at a pressure of P=56atm and a temperature T=450K using the Van Der Waals equation of state. 2. Repeat the calculations for the following reduced pressure: Pr?=1,2,4,10, and 20. 3. How does the compressibility factor vary a function of Pr? ? Draw Z versus Pr using Excel.