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(Solved): The Arrhenius equation shows the relationship between the rate constant k and the temperature T in k ...



The Arrhenius equation shows the relationship between the rate constant

k

and the temperature

T

in kelvins and is typically written as

k=Ae^(-(E_(a))/(R)T)

where

R

is the gas constant

(8.314(J)/(m)ol*K)

,

A

is a constant called the frequency factor, and

E_(a)

is the activation energy for the reaction. However, a more practical form of this equation is

ln((k_(2))/(k_(1)))=(E_(2))/(R)((1)/(T_(1))-(1)/(T_(2)))

which is mathmatically equivalent to

ln((k_(1))/(k_(2)))=(E_(a))/(R)((1)/(T_(2))-(1)/(T_(1)))

where

k_(1)

and

k_(2)

are the rate constants for a single reaction at two different absolute temperatures (

T_(1)

and

T_(2)

). The activation energy of a certain reaction is

47.4k(J)/(m)ol

. At

26\deg C

, the rate constant is

0.0120s^(-1)

. At what temperature in degrees Celsius would this reaction go twice as fast? Express your answer with the appropriate units. View Available Hint(s)

?

q,

Part B Given that the initial rate constant is

0.0120s^(-1)

at an initial temperature of

26\deg C

, what would the rate constant be at a temperature of 200 .

\deg C

for the same reaction described in Part A? Express your answer with the appropriate units. View Available Hint(s)

k_(2)=

?
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