The Arrhenius equation shows the relationship between the rate constant
k
and the temperature
T
in kelvins and is typically written as
k=Ae^(-(E_(a))/(R)T)
where
R
is the gas constant
(8.314(J)/(m)ol*K)
,
A
is a constant called the frequency factor, and
E_(a)
is the activation energy for the reaction. However, a more practical form of this equation is
ln((k_(2))/(k_(1)))=(E_(2))/(R)((1)/(T_(1))-(1)/(T_(2)))
which is mathmatically equivalent to
ln((k_(1))/(k_(2)))=(E_(a))/(R)((1)/(T_(2))-(1)/(T_(1)))
where
k_(1)
and
k_(2)
are the rate constants for a single reaction at two different absolute temperatures (
T_(1)
and
T_(2)
). The activation energy of a certain reaction is
47.4k(J)/(m)ol
. At
26\deg C
, the rate constant is
0.0120s^(-1)
. At what temperature in degrees Celsius would this reaction go twice as fast? Express your answer with the appropriate units. View Available Hint(s)
?
q,
Part B Given that the initial rate constant is
0.0120s^(-1)
at an initial temperature of
26\deg C
, what would the rate constant be at a temperature of 200 .
\deg C
for the same reaction described in Part A? Express your answer with the appropriate units. View Available Hint(s)
k_(2)=
?