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(Solved): The decomposition of nitramide, O_(2)NNH_(2), in water has the chemical equation and rate law O_(2)N ...



The decomposition of nitramide,

O_(2)NNH_(2)

, in water has the chemical equation and rate law

O_(2)NNH_(2)(aq)longrightarrowN_(2)O(g)+H_(2)O(l), rate =k([O_(2)NNH_(2)])/([H^(+)])

A proposed mechanism for this reaction is

O_(2)NNH_(2)(aq)?_(k_(-1))^(k_(1))O_(2)NNH^(-)(aq)+H^(+)(aq),

(fast equilibrium)

O_(2)NNH^(-)(aq)->k_(2)N_(2)O(g)+OH^(-)

(aq) (slow)

H^(+)(aq)+OH^(-)(aq)->k_(3)H_(2)O

(1) (fast)



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